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基于二维材料的红外探测器研究:进展与挑战

Research on Infrared Detectors Based on 2D Materials: Progress and Challenges

  • 摘要: 红外探测器在军事、工业、医疗等领域至关重要,但传统材料存在局限:硅基仅覆盖近红外,HgCdTe大尺寸制备难且需低温,GaAs成本高、含剧毒砷。二维(2D)材料因原子级厚度、可调带隙、宽光谱响应等优势,成为突破瓶颈的关键。本文综述其研究进展:先阐述光电导、光伏等5种核心工作机制,及响应率、比探测率等关键性能指标;再分析三类代表性2D材料探测器——石墨烯实现0.76μm至太赫兹超宽探测,过渡金属硫族化合物(TMDs)通过层数调控带隙适配近中红外,黑磷经As掺杂改善稳定性。针对2D材料光吸收弱等问题,总结优化策略:缺陷工程、异质结调控、结构创新,部分器件响应度达105A/W、探测率1014Jones。当前面临规模化制备难、材料易氧化、性能权衡瓶颈。未来需开发新型2D材料、突破批量制备技术,面向可穿戴、深空探测等场景定制器件,有望5-10年内实现关键领域商用替代。

     

    Abstract: Infrared detectors play a crucial role in military, industrial, and medical fields. However, traditional materials have limitations: silicon-based detectors only cover the near-infrared range, HgCdTe is difficult to fabricate in large sizes and requires low temperatures, and GaAs is expensive and contains highly toxic arsenic. 2D materials, with their atomic-level thickness, tunable bandgap, and wide spectral response, have emerged as a key to breaking through these bottlenecks. This paper reviews the research progress: it first elaborates on five core working mechanisms such as photoconductive (PCE) and photovoltaic (PVE), as well as key performance indicators like responsivity and specific detectivity. Then, it analyzes three representative 2D material detectors: graphene achieving ultra-wide detection from 0.76 μm to terahertz, TMDs adapting to near and mid-infrared by layer number control, and black phosphorus improving stability through As doping. To address issues such as weak light absorption in 2D materials, optimization strategies are summarized: defect engineering, heterojunction regulation, and structural innovation, with some devices achieving responsivity up to 105 A/W and detectivity of 1014 Jones. Currently, challenges include difficult large-scale fabrication, material oxidation, and performance trade-offs. In the future, the development of new 2D materials and breakthroughs in batch fabrication techniques are needed, with customized devices for wearable and deep space exploration applications expected to achieve commercial substitution in key fields within 5-10 years.

     

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